The two keys PrintScrn/SysRq and Pause/Break are special in that they have two keycodes: the former has keycode 84 when Alt is pressed simultaneously, and keycode 99 otherwise; the latter has keycode 101 when Ctrl is pressed simultaneously, and keycode 119 otherwise. (Thus, it makes no sense to bind functions to Alt keycode 99 or Ctrl keycode 119.) The Pause/Break key is also special in another way: it does not generate key-up scancodes, but generates the entire 6-scancode sequence on key-down.
If you have strange keys, that do not generate any code under
Linux (or generate messages like "unrecognized scancode"), and
your kernel is 1.1.63 or later, then you can use setkeycodes(1)
to tell the kernel about them. Once they have gotten a keycode
from setkeycodes, they can be assigned a function by
loadkeys.
For example, using showkey -s one sees that
Microsoft keyboards use the scancode sequences (in hexadecimal)
e0 5b (left Windows key), e0 5c (right Windows key), e0 5d (Menu
key). Microsoft Internet keyboard also uses e0 6a (Back), e0 69
(Forward), e0 68 (Stop), e0 6c (Mail), e0 65 (Search), e0 66
(Favorites), e0 32 (Web/Home), e0 6b (My Computer), e0 21
(Calculator), e0 5f (Sleep). Use dumpkeys to see
what keycodes are still unused. Typically values like 89-95 and
112-118 and 120-127 are free. Now
assigns keycodes to these scancode sequences, and% setkeycodes e05b 125 % setkeycodes e05c 126 % setkeycodes e05d 127
would make these Windows keys go to the previous or next virtual console, and let the Menu key create a fresh virtual console (in case you have something like% loadkeys keycode 125 = Decr_Console keycode 126 = Incr_Console keycode 127 = KeyboardSignal %
spawn_console
running).
Many modern keyboards have buttons or keys with labels like "Vol
Up", "Eject" etc. that suggest actions rather than strings. Of
course one can bind shell commands to them, but then they'll work
only when you are at a shell prompt. Rick van Rein wrote a
package funkey consisting of a kernel patch and a daemon. The
kernel patch creates a new character device, and adds a new key
type to indicate which keystrokes should be sent to this new
character device. A daemon can now listen to the character
device, somewhat like gpm listens to the mouse
device, and perform the actions indicated in its config file. See
rick.vanrein.org/linux/funkey.